JOURNAL OF SHANDONG UNIVERSITY (ENGINEERING SCIENCE) ›› 2009, Vol. 39 ›› Issue (3): 62-66.

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Synthesis of (La0.8Sr0.2)0.9MnO3-δ powder by a gel-casting technique as cathodes for solid oxide fuel cells

 Zhang Yu-jun,ZHANG Lan,JIANG San-ping    

  1.  Zhang Yu-jun  ZHANG Lan:Key Lab for Liquid Structures and Heredity of Materials of Education Ministry, Shandong University, Shandong 250061, China; ZHANG Lan  JIANG San-ping :School of Mechanical and Aerospace Engineering, Nanyang Technological University, Singapore 639798
  • Received:2008-09-28 Online:2009-06-16 Published:2009-06-16

Abstract:

 (La0.8Sr0.2)0.9MnO3-δ (LSM) powders were successfully synthesized via a gel-casting technique and traditional solid state reaction method by using oxide and carbon as raw materials. The perovskite phase formation temperature of LSM powders synthesized by the gel-casting technique was about 850℃, which is nearly 150℃ lower than that of LSM powders synthesized by the conventional solid-state reaction route. The significantly reduced phase formation temperature of the gel-casting LSM powder was most likely due to the homogeneously distributed and immobilized precursor particles in a polymeric network, which promoted the sintering and crystallization process. Furthermore, the electrochemical catalytic performance of LSM electrodes prepared by LSM powders synthesized gel-casting technique and sintered at different temperature was also investigated in detail.

Key words: , gel-casting, solid state reaction, solid oxide fuel cell,  , (La0.8Sr0.2)0.9MnO3-&delta

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