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山东大学学报(工学版)

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IIb型与Ib型金刚石热稳定性比较

王美1,2, 李和胜1,2, 李木森1,2, 田彬1,2   

  1. 1. 山东大学材料科学与工程学院,山东济南250061;2. 山东省超硬材料工程技术研究中心,山东邹城273500
  • 收稿日期:2007-01-10 修回日期:1900-01-01 出版日期:2007-12-24 发布日期:2007-12-24
  • 通讯作者: 王美

Thermal stability comparison of the IIb type and the Ib type diamond

WANG Mei1,2,LI Hesheng1,2,LI Musen1,2,TIAN Bin1,2   

  1. 1. School of Materials Science and Engineering,Shandong University,Jinan 250061,China;2. Shandong Engineering Research Center for Super Hard Materials,Zoucheng 273500,China
  • Received:2007-01-10 Revised:1900-01-01 Online:2007-12-24 Published:2007-12-24
  • Contact: WANG Mei

摘要: 通过在铁基触媒中加入氮化硼的方法,高温高压合成了IIb型金刚石.用光学显微镜对IIb型金刚石与Ib型金刚石的单晶形貌结构进行观察.利用冲击韧性测定仪、静压强度仪及差热分析仪对IIb型金刚石与Ib型金刚石在空气中的热稳定性进行了系统的对比研究.结果一致表明,合成的IIb型金刚石较Ib型金刚石不仅具有优异的热冲击韧性和静压强度,而且具有较好的热稳定性,并通过差热分析提出了进一步提高金刚石热稳定性的有效地途径.金刚石的热分解过程与其重量的损失是同步的,表明失重是由金刚石石墨化和氧化引起的.

关键词: IIb金刚石, 高温高压, 热冲击韧性, 静压强度, 热稳定性

Abstract: The IIb type diamond was synthesized at high temperature and high pressure (HTHP) by using the technique of adding BN in Febased catalyst. The appearance of the IIb type and the Ib type diamond was studied under opticsmicroscope. Static compressive strength measurement, impact toughness measurement and DTA and TG analysis were used to research thermal stability of these two types of diamond in atmosphere. The results demonstrate that the IIb type diamond possesses not only fine static compressive strength and thermal impact toughness, but also owns excellent thermal stability. In addition, an available way is put forward to improve the thermal stability of diamond. Thermal decompose and mass loss of diamond happened at the same time shows that it is graphitization and oxidation of diamond causes the mass loss.

Key words: the IIb type diamond, high temperature and high pressure, thermal impact toughness, static compressive strength, thermal stability

中图分类号: 

  • TQ164
[1] 李和胜,李木森, . 铁基触媒合成金刚石的压力功率动态匹配工艺研究[J]. 山东大学学报(工学版), 2006, 36(6): 1-05 .
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