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山东大学学报 (工学版) ›› 2025, Vol. 55 ›› Issue (1): 149-156.doi: 10.6040/j.issn.1672-3961.0.2023.327

• 化学与环境 • 上一篇    下一篇

快速溶剂-固相萃取法测定土壤中多溴联苯醚

龚飞杰1,齐安安1,李一凡1,张雄飞1,黄琦1,杨凌霄1,2*   

  1. 1.山东大学环境研究院, 山东 青岛 266237;2.江苏省气候变化协同创新中心, 江苏 南京 210023
  • 出版日期:2025-02-20 发布日期:2025-02-20
  • 作者简介:龚飞杰(1999— ),男,福建宁德人,硕士研究生,主要研究方向为持久性有机污染物的分布、来源解析. E-mail:gongfeijie1130@163.com. *通信作者简介:杨凌霄(1973— ),女,河南开封人,教授,博士生导师,博士,主要研究方向为大气细颗粒物化学组分污染特征、来源及形成机制和区域雾霾形成机制、危害及防控机制. E-mail:yanglingxiao@sdu.edu.cn
  • 基金资助:
    青岛市自然科学基金资助项目(23-2-1-224-zyyd-jch)

Determination of PBDEs in soil byhigh performance solvent extraction-solid phase extraction

GONG Feijie1, QI Anan1, LI Yifan1, ZHANG Xiongfei1, HUANG Qi1, YANG Lingxiao1,2*   

  1. GONG Feijie1, QI Anan1, LI Yifan1, ZHANG Xiongfei1, HUANG Qi1, YANG Lingxiao1, 2* (1. Environmental Research Institute, Shandong University, Qingdao 266237, Shandong, China;
    2. Jiangsu Collaborative Innovation Center for Climate Change, Nanjing 210023, Jiangsu, China
  • Online:2025-02-20 Published:2025-02-20

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摘要： 为建立快速、简便地分析土壤中12种多溴联苯醚(polybrominated diphenyl ethers, PBDEs)质量分数的检测方法,对仪器的参数和样品净化过程进行了优化。通过对比不同仪器参数组合、固相萃取柱种类、活化和洗脱溶剂组合及溶剂洗脱量对样品中12种PBDEs回收率的影响,确定了最优条件。在最优条件下,对实际土样进行加标验证,12种PBDEs的平均加标回收率为90.36%~121.40%,回收率相对标准偏差为4.11%~8.76%,东营油田土壤中PBDEs的质量分数为6.68×10-9~105.68×10-9。本方法使用C18固相萃取柱替代传统复合硅胶柱,简化了样品处理过程,具备操作便捷、稳定性好的优点,适用于大规模土壤样品中PBDEs的检测。

关键词: 快速溶剂萃取, 多溴联苯醚, 土壤, 气相色谱-质谱法, 固相萃取

中图分类号: 

  • X513
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