您的位置：山东大学 -> 科技期刊社 -> 《山东大学学报（工学版）》

山东大学学报 (工学版) ›› 2020, Vol. 50 ›› Issue (1): 109-114.doi: 10.6040/j.issn.1672-3961.0.2019.359

• 化学与环境 • 上一篇    下一篇

钛盐混凝剂的研究进展

高宝玉1(),黄鑫1,姚广平2,岳钦艳1   

  1. 1. 山东大学环境科学与工程学院, 山东 济南 250100
    2. 山东山大华特科技股份有限公司, 山东 济南 250061
  • 收稿日期:2019-07-08 出版日期:2020-02-20 发布日期:2020-02-14
  • 作者简介:高宝玉(1961—)，男，山东鄄城人，博士，教授，研究方向为混凝剂及混凝技术. E-mail: baoyugao_sdu@aliyun.com|高宝玉，男，1961年7月生，工学博士，山东大学特聘教授和二级岗位教授，博士生导师。2001—2012任山东大学环境科学与工程学院院长。享受国务院政府特殊津贴，泰山学者特聘专家，山东省有突出贡献的中青年专家，山东省优秀科技工作者，济南“泉城学者”，济南专业技术拔尖人才，注册环保工程师。主要从事水和废水处理用药剂、材料与技术研发工作。承担了国家级及省部级等科研项目60余项，鉴定成果25项，授权发明专利89件，发表学术论文780余篇(其中被SCI收录530余篇，被SCI他引15 300余次，h-index为62)，研究成果获国际、国家及省部级等各种奖励26项，出版专著5部。入选爱思唯尔(Elsevier)发布的2014、2015、2016、2017和2018年中国高被引学者(Most Cited Chinese Researchers)环境科学领域榜单。目前兼任《Journal of Environmental Sciences》《Journal of Water Sustainability》《中国环境科学》和《环境科学》等十余种学术期刊的编委

Review of developments in titanium-based coagulants

Baoyu GAO1(),Xin HUANG1,Guangping YAO2,Qinyan YUE1   

  1. 1. School of Environmental Science and Engineering, Shandong University, Jinan 250100, Shandong, China
    2. Shandong Shanda Huate Science and Technology Co., Ltd., Jinan 250061, Shandong, China
  • Received:2019-07-08 Online:2020-02-20 Published:2020-02-14

RichHTML

50

PDF (PC)

860

摘要：

对钛盐混凝剂的发展历程及其在水处理中的应用研究进行了综合评述，包括简单的低分子钛盐混凝剂及高分子聚合钛盐混凝剂的研究、单一的钛盐混凝剂及复合钛盐混凝剂的研究以及钛盐混凝剂的研究现状与其未来发展趋势，为其在水处理领域的进一步研究发展提供了指导和参考。

关键词: 钛盐, 混凝剂, 水处理, 强化混凝, 复合药剂

Abstract:

The development process and its applications of titanium-based coagulant were reviewed, including the mono-titanium coagulants and poly-titanium coagulants, and the single titanium coagulants and composite titanium coagulants, and the recent research process and the future development of titanium coagulants, which could provide guidances and references for the research and development of titanium-based coagulants.

Key words: titanium salts, coagulants, water treatment, enhanced coagulation, composite coagulant

中图分类号: 

  • X13
1 SHON H K , VIGNESWARAN S , KIM I S , et al. Preparation of titanium dioxide (TiO2) from sludge produced by titanium tetrachloride (TiCl4) flocculation of waste-water[J]. Environmental Science & Technology, 2007, 41 (4): 1372- 1377.
2 邓国珠. 世界钛资源及其开发利用现状[J]. 钛工业进展, 2002, (5): 9- 12.
doi: 10.3969/j.issn.1009-9964.2002.05.003
DENG Guozhu . Titfnium resources and their development and utilization in the world[J]. Titanium industry development, 2002, (5): 9- 12.
doi: 10.3969/j.issn.1009-9964.2002.05.003
3 WU Yifan , LIU Wen , GAO Naiyun , et al. A study of titanium sulfate flocculation for water treatment[J]. Water Research, 2011, 45 (12): 3704- 3711.
doi: 10.1016/j.watres.2011.04.023
4 董胜璋, 黎大明, 牛冠明, 等. 钛经口摄入毒性试验[J]. 毒理学杂志, 1992, 6 (2): 98- 99.
DONG Shengzhang , LI Daming , NIU Guanming , et al. Toxicity test of titanium by oral ingestion[J]. Journal of Toxicology, 1992, 6 (2): 98- 99.
5 UPTON W V , BUSWELL A M . Titanium salts in water purification[J]. Industrial & Engineering Chemistry, 1937, 29 (8): 870- 871.
6 OKOUR Y , SHON H K , El Saliby I . Characterisation of titanium tetrachloride and titanium sulfate flocculation in wastewater treatment[J]. Water Science and Technology, 2009, 59 (12): 2463- 2473.
doi: 10.2166/wst.2009.254
7 ZHAO Y X , GAO B Y , SHON H K , et al. Coagulation characteristics of titanium (Ti) salt coagulant compared with aluminum (Al) and iron (Fe) salts[J]. Journal of Hazardous Materials, 2011, 185 (2-3): 1536- 1542.
doi: 10.1016/j.jhazmat.2010.10.084
8 ZHAO Y X , SHON H K , PHUNTSHOP S , et al. Removal of natural organic matter by titanium tetrachloride: the effect of total hardness and ionic strength[J]. Journal of Environmental Management, 2014, 134, 20- 29.
doi: 10.1016/j.jenvman.2014.01.002
9 ZHAO Y X , GAO B Y , SHON H K , et al. Characterization of coagulation behavior of titanium tetrachloride coagulant for high and low molecule weight natural organic matter removal:the effect of second dosing[J]. Chemical Engineering Journal, 2013, 228, 516- 525.
doi: 10.1016/j.cej.2013.05.042
10 HUSSAIN S , VAN Leeuwen J , CHOW C W K , et al. Comparison of the coagulation performance of tetravalent titanium and zirconium salts with alum[J]. Chemical Engineering Journal, 2014, 254, 635- 646.
doi: 10.1016/j.cej.2014.06.014
11 HUANG X , GAO B , ZHAO S , et al. Application of titanium sulfate in a coagulation-ultrafiltration process: a comparison with aluminum sulfate and ferric sulfate[J]. RSC Adv, 2016, 6 (55): 49469- 49477.
doi: 10.1039/C6RA05075A
12 彭艳.钛盐及复合钛铁盐混凝剂的制备及其对饮用水中砷的去除研究[D].合肥:安徽建筑工业学院, 2012.
PENG Yan. Preparation of titanium salt and Ti-Fe coagulant and their properties for arsenic removal from drinking water[D]. Hefei: Anhui University of Architecture, 2012.
13 SUN Y , ZHOU G , XIONG X , et al. Enhanced arsenite removal from water by Ti(SO4)2 coagulation[J]. Water Research, 2013, 47 (13): 4340- 4348.
doi: 10.1016/j.watres.2013.05.028
14 沈珺.钛盐混凝与钛氢氧化物吸附去除饮用水中砷的研究[D].合肥:安徽建筑大学, 2015.
SHEN Jun. Performance study of arsenic removal during the titanium salt coagulation and titanium hydroxide adsorption process[D]. Hefei: Anhui Jianzhu University, 2015.
15 沈珺, 唐玉朝, 黄显怀, 等. 钛盐混凝去除水中As(Ⅲ)的性能研究[J]. 水处理技术, 2015, (8): 61- 66.
SHEN Jun , TANG Yuchao , HUANG Xianhuai , et al. Study on the performance of As (Ⅲ) removal from water by titanium salt coagulation[J]. Technology of Water Treatment, 2015, (8): 61- 66.
16 李优平.钛盐混凝去除无机As(Ⅲ)的实验研究[D].西安:西安建筑科技大学, 2014.
LI Youping. Removal of inorganic As (Ⅲ) by titanium salt coagulation[D]. Xi'an: Xi'an University of Architecture and Technology, 2014.
17 李优平, 王玉霞, 段晋明, 等. 硫酸钛混凝去除无机砷(Ⅲ)的效能[J]. 环境工程学报, 2015, 9 (6): 2875- 2879.
LI Youping , WANG Yuxia , DUAN Jinming , et al. Removal efficiency of As(Ⅲ) by titanium sulfate coagulation[J]. Chinese Journal of Environmental Engineering, 2015, 9 (6): 2875- 2879.
18 WANG Y , DUAN J , LI W , et al. Aqueous arsenite removal by simultaneous ultraviolet photocatalytic oxidation-coagulation of titanium sulfate[J]. Journal of Hazardous Materials, 2015, 303 (1 Embryonic Ori): 162- 170.
19 王玉霞.铁盐混凝去除As(Ⅲ)和As(Ⅴ)及钛盐光催化氧化混凝去除As(Ⅲ)的机理研究[D].西安:西安建筑科技大学, 2015.
WANG Yuxia. Mechanism of As(Ⅲ) and As(Ⅴ) removal by coagulation of ferric salts and As(Ⅲ) removal by simultaneous phtocatalytic oxidation-coagulation of Titanium salts[D]. Xi'an: Xi'an University of Architecture and Technology, 2015.
20 ZHAO Y , SUN Y , TIAN C , et al. Titanium tetrachloride for silver nanoparticle-humic acid composite contaminant removal in coagulation-ultrafiltration hybrid process: floc property and membrane fouling[J]. Environ Sci Pollut Res Int, 2017, 24 (2): 1757- 1768.
doi: 10.1007/s11356-016-7813-8
21 ZHAO Y X , PHUNTSHO S , GAO B Y , et al. Preparation and characterization of novel polytitanium tetrachloride coagulant for water purification[J]. Environmental Science & Technology, 2013, 47 (22): 12966- 12975.
22 CHEKL L , GALLOUS J , ZHAO Y X , et al. Coagulation performance and floc characteristics of polytitanium tetrachloride (PTC) compared with titanium tetrachloride (TiCl4) and iron salts in humic acid-kaolin synthetic water treatment[J]. Separation and Purification Technology, 2015, 142, 155- 161.
doi: 10.1016/j.seppur.2014.12.043
23 ZHAO Y X , PHUNTSHO S , GAO B Y , et al. Comparison of a novel polytitanium chloride coagulant with polyaluminium chloride: coagulation performance and floc characteristics[J]. Journal Of Environmental Management, 2015, 147, 194- 202.
24 GALLOUX J , CHEKLI L , PHUNTSHO S , et al. Coagulation performance and floc characteristics of polytitanium tetrachloride and titanium tetrachloride compared with ferric chloride for coal mining wastewater treatment[J]. Separation and Purification Technology, 2015, 152, 94- 100.
doi: 10.1016/j.seppur.2015.08.009
25 CHEKLI L , ERPRET C , PARK S H , et al. Coagulation performance and floc characteristics of polytitanium tetrachloride (PTC) compared with titanium tetrachloride (TiCl4) and ferric chloride (FeCl3) in algal turbid water[J]. Separation and Purification Technology, 2017, 175, 99- 106.
doi: 10.1016/j.seppur.2016.11.019
26 ZHAO Y , PHUNTSHO S , GAO B , et al. Polytitanium sulfate (PTS): coagulation application and Ti species detection[J]. Journal of Environmental Science, 2017, 52, 250- 258.
doi: 10.1016/j.jes.2016.04.008
27 WANG X , LI M , SONG X , et al. Preparation and Evaluation of titanium-based xerogel as a promising coagulant for water/wastewater treatment[J]. Environmental Science & Technology, 2016, 50 (17): 9619- 9626.
28 ZHANG W , CHEN Z , CAO B , et al. Improvement of wastewater sludge dewatering performance using titanium salt coagulants (TSCs) in combination with magnetic nano-particles: Significance of titanium speciation[J]. Water Research, 2017, 110, 102- 111.
doi: 10.1016/j.watres.2016.12.011
29 ZHAO Y X , GAO B Y , RONG H Y , et al. The impacts of coagulant aid-polydimethyldiallylammonium chloride on coagulation performances and floc characteristics in humic acid-kaolin synthetic water treatment with titanium tetrachloride[J]. Chemical Engineering Journal, 2011, 173 (2): 376- 384.
doi: 10.1016/j.cej.2011.07.071
30 ZHAO Y X , GAO B Y , QI Q B , et al. Cationic polyacrylamide as coagulant aid with titanium tetrachloride for low molecule organic matter removal[J]. Journal of Hazardous Materials, 2013, 258-259, 84- 92.
doi: 10.1016/j.jhazmat.2013.04.044
31 ZHAOY X , GAO B Y , SHON H K , et al. Anionic polymer compound bioflocculant as a coagulant aid with aluminum sulfate and titanium tetrachloride[J]. Bioresour Technol, 2012, 108, 45- 54.
doi: 10.1016/j.biortech.2012.01.012
32 HUANG X , GAO B , RONG H , et al. Effect of using polydimethyldiallylammonium chloride as coagulation aid on polytitanium salt coagulation performance, floc properties and sludge reuse[J]. Separation and Purification Technology, 2015, 143, 64- 71.
doi: 10.1016/j.seppur.2015.01.024
33 HUANG X , ZHAO Y , GAO B , et al. Polyacrylamide as coagulant aid with polytitanium sulfate in humic acid-kaolin water treatment: effect of dosage and dose method[J]. Journal of the Taiwan Institute of Chemical Engineers, 2016, 64, 173- 179.
doi: 10.1016/j.jtice.2016.04.011
34 HUANG X , GAO B , SUN Y , et al. Effects of epichlorohydrin-dimethylamine on polytitanium chloride coagulation and membrane fouling in humic-kaolin water treatment: dosage, dose method and solution pH[J]. Separation and Purification Technology, 2017, 173, 209- 217.
doi: 10.1016/j.seppur.2016.09.035
35 刘娟.基于钛盐的无机高分子复合絮凝剂的制备及其结构和性能研究[D].武汉:武汉科技大学, 2010.
LIU Juan. Study on inorganic polymeric flocculant titanium-based (Ti-IPF)-synthesis, Structure and coagulation performance[D]. Wuhan: Wuhan University of Science and Technology, 2010.
36 李肖.无机高分子助凝剂聚硅酸钛的制备及其特性研究[D].西安:西安建筑科技大学, 2014.
LI Xiao. Preparation and characteristics of inorganic polymeric coagulant aid-polysilicate-titanium[D]. Xi'an: Xi'an University of Architecture and Technology, 2014.
37 HUANG X , GAO B , WANG Y , et al. Coagulation performance and flocs properties of a new composite coagulant: Polytitanium-silicate-sulfate[J]. Chemical Engineering Journal, 2014, 245, 173- 179.
doi: 10.1016/j.cej.2014.02.018
38 HUANG X , GAO B , YUE Q , et al. Effect of Si/Ti molar ratio on enhanced coagulation performance, floc properties and sludge reuse of a novel hybrid coagulant: polysilicate titanium sulfate[J]. Desalination, 2014, 352, 150- 157.
doi: 10.1016/j.desal.2014.08.021
39 HUANG X , GAO B , SUN Y , et al. Effects of solution pH and synthetic method on destabilization process of polytitanium-silicate-chloride[J]. Journal of Hazardous Materials, 2016, 311, 230- 236.
doi: 10.1016/j.jhazmat.2016.03.021
40 HUANG X , GAO B , YUE Q , et al. Characterization and application of a novel inorganic polymer coagulant: polytianium-silicate-chloride[J]. RSC Adv, 2016, 6 (30): 24898- 24905.
doi: 10.1039/C6RA01333C
41 王景芝.聚硅钛铁净水剂制备及其对腐殖酸模拟水的混凝实验[D].济南:济南大学, 2016.
WANG Jingzhi. Preparation of poly-Ti-Fe-Si water purifying agent and coagulation test for simulated humic acid water[D]. Jinan: Jinan University, 2016.
42 陈毛毛.赤泥制备含钛聚硅酸铝铁混凝剂及其应用研究[D].呼和浩特:内蒙古科技大学, 2015.
CHEN Maomao. Perparation and application of titanium-containing polysilicate-aluminium-iron coagulant from red mud[D]. Hohhot: Inner Mongolia University of Science and Technology, 2015.
43 薛文文.聚硫酸铁钛混凝剂(PFTS)的制备及在饮用水处理中的应用[D].重庆:重庆大学, 2015.
XUE Wenwen. Preparation of poly ferric titanium sulfate (PFTS) and utilization in drinking water treatment[D]. Chongqing: Chongqing University, 2015.
44 刘维, 吴冰, 曹江林, 等. 钛对聚合硫酸铁制备与性能的影响[J]. 环境化学, 2012, 31 (4): 437- 442.
LIU Wei , WU Bing , CAO Jianglin , et al. Effect of titanium on preparation and properties of polyferric sulfate[J]. Environmental Chemistry, 2012, 31 (4): 437- 442.
45 陈伟.铁钛混凝剂的制备及在除藻和控制藻源膜污染中的应用研究[D].重庆:重庆大学, 2016.
CHEN Wei. The preparation of Fe-Ti based coagulant and its application in algae removal and membrane fouling controlling[D]. Chongqing: Chongqing University, 2016.
[1] 刘鸿斌,宋留. 废水处理过程的典型相关分析建模方法研究[J]. 山东大学学报 (工学版), 2020, 50(1): 101-108.
[2] 杨冬璐,马逍天,洪静兰. 基于生命周期评价的造纸废水的水足迹[J]. 山东大学学报 (工学版), 2019, 49(3): 114-119, 128.
[3] 孙翠平, 周维芝, 赵海霞. 铁强化微生物除磷的效能及机理[J]. 山东大学学报(工学版), 2015, 45(2): 82-88.
[4] 饶敏1,李燕红1,陈伟华1,宋建波2,陈广大1,刘晓作1. 二硝基重氮酚工业废水处理研究[J]. 山东大学学报(工学版), 2012, 42(6): 100-106.
[5] 余锋俊,施来顺*. 二氧化锰催化二氧化氯氧化酸性铬蓝K模拟废水[J]. 山东大学学报(工学版), 2010, 40(2): 88-94.
[6] 张永强 高宝玉 卢磊 曹百川. 混凝法处理胜利油田聚合物驱采出水效果研究[J]. 山东大学学报(工学版), 2010, 40(1): 98-102.
[7] 王静,李玉江,张晓瑾, 毕研俊,陈位锁 . 粉煤灰去除水中活性紫KN-B[J]. 山东大学学报(工学版), 2006, 36(6): 100-103 .
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed   
[1] 施来顺,万忠义 . 新型甜菜碱型沥青乳化剂的合成与性能测试[J]. 山东大学学报(工学版), 2008, 38(4): 112 -115 .
[2] 孔祥臻,刘延俊,王勇,赵秀华 . 气动比例阀的死区补偿与仿真[J]. 山东大学学报(工学版), 2006, 36(1): 99 -102 .
[3] 陈瑞,李红伟,田靖. 磁极数对径向磁轴承承载力的影响[J]. 山东大学学报(工学版), 2018, 48(2): 81 -85 .
[4] 李可,刘常春,李同磊 . 一种改进的最大互信息医学图像配准算法[J]. 山东大学学报(工学版), 2006, 36(2): 107 -110 .
[5] 季涛,高旭,孙同景,薛永端,徐丙垠 . 铁路10 kV自闭/贯通线路故障行波特征分析[J]. 山东大学学报(工学版), 2006, 36(2): 111 -116 .
[6] 秦通,孙丰荣*,王丽梅,王庆浩,李新彩. 基于极大圆盘引导的形状插值实现三维表面重建[J]. 山东大学学报(工学版), 2010, 40(3): 1 -5 .
[7] 刘文亮,朱维红,陈涤,张泓泉. 基于雷达图像的运动目标形态检测及跟踪技术[J]. 山东大学学报(工学版), 2010, 40(3): 31 -36 .
[8] 孙国华,吴耀华,黎伟. 消费税控制策略对供应链系统绩效的影响[J]. 山东大学学报(工学版), 2009, 39(1): 63 -68 .
[9] 王,张艳宁,申家振,刘俊成 . 基于信息测度和支持向量机的图像边缘检测[J]. 山东大学学报(工学版), 2006, 36(3): 95 -99 .
[10] 李芳佳, 高尚策, 唐政, 石井雅博, 山下和也. 基于元胞自动化模型的三维雪花晶体近似模式的产生（英文）[J]. 山东大学学报(工学版), 2009, 39(1): 102 -105 .
版权所有 © 2018 《山东大学学报(工学版)》编辑部　
地址: 济南市山大南路27号（250100）　 电话: 0531-88366735　 E-mail: xbgxb@sdu.edu.cn
本系统由北京玛格泰克科技发展有限公司设计开发