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山东大学学报(工学版) ›› 2010, Vol. 40 ›› Issue (3): 75-79.

• 材料科学与工程 • 上一篇    下一篇

莱钢120吨转炉冶炼超低硫钢工艺优化

王庆春1,李木森2,范树璐3,张继军3   

  1. 1. 山东工业职业学院冶金学院, 山东 淄博 256414; 2.山东大学材料科学与工程学院, 山东 济南 250061;
    3. 莱钢集团公司, 山东 莱芜 271126
  • 收稿日期:2009-12-24 出版日期:2010-06-16 发布日期:2009-12-24
  • 作者简介:王庆春(1964-),男,山东栖霞人,副教授,主要研究方向为冶金工程. E-mail:yjxy0533@163.com
  • 基金资助:

    2008年度山东省高等学校优秀青年教师国内访问学者计划资助项目

The optimization of ultra-low sulfur steels produced by the 120t converter system in the Laiwu Iron & Steel Group

WANG Qing-chun1, LI Mu-sen2, FAN Shu-lu3, ZHANG Ji-jun3   

  1. 1. Metallurgical Institue,Shandong Vocational College of Industry, Zibo 256414, China;
    2. School of Material Science & Engineering, Shandong University, Jinan 250061, China;
    3. Laiwu Iron & Steel Group, Laiwu 271126, China
  • Received:2009-12-24 Online:2010-06-16 Published:2009-12-24

摘要:

结合脱硫反应热力学和动力学理论,对莱钢120t转炉冶炼过程及操作制度进行了分析研究,通过控制转炉回硫对深脱硫工艺流程进行了优化。结果表明:(1)通过控制转炉回硫,可将LF炉中钢水硫质量分数控制在0.005%以下,脱硫率可达80%以上,终点硫质量分数最低可达到0.001%,并且能够稳定生产硫质量分数小于0.005%的低硫钢种;(2)顶渣SiO2质量分数可控制在8%以下;(3)终点(FeO+MnO)质量分数和可降低到1%左右,碱度可控制在5~6之间。

关键词: 转炉回硫, 顶渣改质, 溅渣护炉, 深脱硫

Abstract:

Based on the thermodynamics and kinetics of desulphurization theory, an ultralow sulfur converter steelmaking process and operation system in the Laigang 120t converter system was analyzed. By controlling the converter resulfurization smelting, the deep desulfurization technological process was optimized. The results showed that the sulfur content can be reduced to below 0.005%. The desulphurization rate can be increased to 80% and therefore the final sulfur content could reach to 0.001%. Consequently, low sulfur steel with sulfur content below 0.005 % could be stably produced. In the following LF refining, SiO2 content in LF top slag could be reduced to below 8%. The final (FeO+MnO) content could be reduced to about 1% and the alkalinity can be controlled between 5 and 6.

Key words: converter resulfurization, top slag improvement, slag splashing protection, deep desulfurization

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