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山东大学学报(工学版) ›› 2010, Vol. 40 ›› Issue (4): 72-74.

• 材料科学与工程 • 上一篇    下一篇

TiO2/ZnO纳米光催化剂的制备及性能研究

徐青, 吕伟*   

  1. 山东大学化学与化工学院, 山东 济南  250100
  • 收稿日期:2009-11-16 出版日期:2010-08-16 发布日期:2009-11-16
  • 通讯作者: 吕伟(1965-),男,山东成武人,副教授,博士,主要研究方向为无机功能纳米材料合成与性质. E-mail:E-mail: lwei@sdu.edu.cn
  • 作者简介:徐青(1983-),女,浙江余姚人,硕士研究生,主要研究方向为无机功能纳米材料合成与性质. E-mail: 748873736@qq.com
  • 基金资助:

    山东省自然科学基金资助项目(Y2008G25);济南市高校自主创新资助项目(200815063)

Preparation and properties of TiO2/ZnO Photocatalyst

XU Qing, LV Wei*   

  1. School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China
  • Received:2009-11-16 Online:2010-08-16 Published:2009-11-16

摘要:

通过二步法(阳极氧化法和水热法)得到结构规则、有序核-壳结构的TiO2/ZnO纳米复合材料,并利用SEM、UV-vis、TEM等方法对所制备的纳米复合材料进行了表征。以甲基橙为目标降解物,自然光为光源,研究了TiO2/ZnO纳米光催化剂的光催化活性。结果表明,TiO2/ZnO复合光催化剂能提高对太阳光的利用率,发现在降解液pH值为3、太阳光催化降解5h时,催化剂的降解效果最好,降解率达90%。

关键词: 二步法, 光催化活性, TiO2/ZnO, 甲基橙

Abstract:

Highly ordered TiO2/ZnO nanocomposites with core-shell structure were successfully fabricated by a two-step method(anodic oxidation and hydrothermal method). The nanocomposites were analyzed by means of a scanning electron microscope (SEM), double beam UV-vis spectrophotometer and transmission electron microscope (TEM). The photocatalytic activity of the prepared material was tested by taking methyl orange as a pollutant on the model and natural light as the light source. The results showed that, TiO2/ZnO composite photocatalyst could improve the utilization of sunlight, and  could show the best  catalytic activity under the condition of pH=3 solution and degraded under the sun for 5 hours,  which reached to 90%.

Key words: two-step method, photoactivity, TiO2/ZnO, methyl orange

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