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山东大学学报(工学版) ›› 2014, Vol. 44 ›› Issue (1): 80-84.doi: 10.6040/j.issn.1672-3961.0.2013.320

• 材料科学与工程 • 上一篇    下一篇

仿蝉翼结构镍磷复合材料减反性能研究

陈挺,覃继宁,范同祥*   

  1. 上海交通大学金属基复合材料国家重点实验室, 上海 200240
  • 收稿日期:2013-11-07 出版日期:2014-02-20 发布日期:2013-11-07
  • 通讯作者: 范同祥(1971- ),男, 山东潍坊人,教授,博导,博士,主要研究方向为仿生功能材料与特种结构金属基功能复合材料. E-mail:txfan@sjtu.edu.cn E-mail:txfan@sjtu.edu.cn
  • 作者简介:陈挺(1988- ),女,浙江乐清人,硕士研究生,主要研究方向为仿生功能材料.Email:chenting0624@sjtu.edu.cn
  • 基金资助:

    国家自然科学基金资助项目(51172141); 教育部博士点基金资助项目(20110073120036)

Anti-reflective property of Ni-P/cicada microstructure composites

CHEN Ting, QIN Jining, FAN Tongxiang*   

  1. State Key Lab of Metal Matrix Composites, Shanghai Jiaotong University, Shanghai 200240, China
  • Received:2013-11-07 Online:2014-02-20 Published:2013-11-07

摘要:

以帝王蝉蝉翼为基底,通过化学镀镍磷的方法,合成了具有纳米点阵结构的镍磷/蝉翼复合材料,并采用扫描电子显微镜、透射电子显微镜、X射线光电子能谱仪以及紫外可见近红外分光光度计等对样品的微观形貌、成分和光学性能进行了测试。在实验基础上,结合三维有限时域差分方法计算了制备样品的反射谱,研究了蝉翼有序纳米点阵结构对镍磷镀层减反性能的影响。研究结果表明,亚波长的有序纳米点阵结构与入射光相互作用,能使镍磷/蝉翼复合材料的反射率比在无蝉翼纳米点阵结构基体上化学镀镍磷材料的反射率降低70%以上,这一研究结果可为制备镍磷减反结构界面提供设计思路。

关键词: 蝉翼, 减反, 镍磷合金, 化学镀, 有限时域差分;纳米点阵

Abstract:

The Ni-P/cicada  wing composites with nano-array structure were prepared by utilizing Pomponia imperatoria wing as the substrates of electroless plating. The microstructures of the samples were characterized by scanning electron microscope (SEM) and transmission electron microscope (TEM), and the component as well as the optical property was respectively tested by X-ray photoelectron spectrometer (XPS) and UV-VIS-NIR spectrophotometer. Moreover, in order to investigate the effect of the nano-array structure on the antireflection property of the Ni-P coating, the 3D finite difference time domain (3D-FDTD) method was used to calculate the reflectance spectra of the synthesized composites based on the experimental data. Result showed that the reflectance of Ni-P/cicada  wing composites with nano-array structure was 70% lower than that of the one without the surface structure, which was ascribed to the interaction between the nanoarray structure and the incident light. This work could provide inspirations for the  antireflective Ni-P surface structure design.

Key words: FDTD, nano-array, cicada wing, anti-reflective, electroless plating, Ni-P alloy

[1] 丁月蕾,刘辉晖,范同祥*. 蝶类纳米点阵复眼结构超黑材料探索研究[J]. 山东大学学报(工学版), 2011, 41(2): 135-139.
[2] 孙从征,管从胜,秦敬玉,程川 . 铝合金化学镀镍磷合金结构和性能[J]. 山东大学学报(工学版), 2007, 37(5): 108-112 .
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