Entransy transfer efficiency, entransy dissipation number and thermal resistance of heat exchanger based on entransy dissipation were applied to heat transfer performance analysis of phase change energy storage heat exchanger on the basis of successful application of entransy theory on conventional heat exchanger. The generalized entransy dissipation rate was defined to derive (instantaneous) entransy transfer efficiency of phase change energy storage heat exchanger in heat storage, heat release and total process, and heat transfer rate was determined to calculate entransy dissipation number and thermal resistance of heat exchanger based on entransy dissipation. A kind of phase change energy storage heat exchanger was selected as the object, and the temperature variation of main parts were described by theoretical analyses. The temperature variation of outlet of silicon oil and water were further simplified to derive their expression, as the basis of calculation and analyses. The results showed that the application range of entransy transfer efficiency was the widest, which was used to calculate the (instantaneous) irreversible heat loss of phase change energy storage heat exchanger in heat storage, heat release and total process. The evaluation results of entransy transfer efficiency were consistent with heat transfer performance and its instantaneous values were increased first, then unchanged, finally increased, with increasing heat storage time, and were decreased first, then unchanged, finally decreased, with increasing heat release time. The evaluation results of entransy dissipation number in heat storage and total process were consistent with that of entransy transfer efficiency. With increasing heat storage time, its instantaneous values were decreased first, then unchanged, finally decreased, while its application was limited in heat release process. The application of thermal resistance of heat exchanger based on entransy dissipation was the most limited since parts of its evaluation results were inconsistent with actual state. In heat storage and total process, the entransy transfer efficiency, entransy dissipation number and thermal resistance of heat exchanger based on entransy dissipation were nearly unchangeable when the heat storage quantity, heat release quantity and stage time in the process of heat storage and release were synchronous. The entransy transfer efficiency was increased, while the entransy dissipation number and the thermal resistance of heat exchanger based on entransy dissipation were decreased when the heat transfer efficiency was improved. In the heat release process, entransy transfer efficiency was unchangeable since the heat transfer performance of system was not influenced by the change of parameters setted.