Journal of Shandong University(Engineering Science) ›› 2023, Vol. 53 ›› Issue (1): 60-67.doi: 10.6040/j.issn.1672-3961.0.2022.176

• Civil Engineering • Previous Articles     Next Articles

The adsorption characteristics of Cu(Ⅱ) on ball clay

Rong CHEN1,2(),Tong WEI1,2,Dongxue HAO1,2,*(),Ke WU3,Ruifeng GUO4   

  1. 1. Institute of Geotechnical Engineering, Northeast Electric Power University, Jilin 132012, Jilin, China
    2. Key Lab of Electric Power Infrastructure Safety Assessment and Disaster Prevention of Jilin Province, Northeast Electric Power University, Jilin 132012, Jilin, China
    3. School of Civil Engineering, Shandong University, Jinan 250100, Shandong, China
    4. Jilin Baofeng Ball Clay Co., Ltd., Jilin 132207, Jilin, China
  • Received:2022-05-08 Online:2023-02-20 Published:2023-02-13
  • Contact: Dongxue HAO E-mail:lg1316cih@126.com;haodongxue2005@126.com

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Abstract:

In order to study the adsorption characteristics of ball clay, the effect of adsorption time, ball clay dosage, pH values and initial concentration of Cu(Ⅱ) were examined by the batch experiments. The results suggested that the adsorption of Cu(Ⅱ) on ball clay was a fast and then slow process. Which almost achieved adsorption equilibrium after 60 minutes and the adsorption capacity and adsorption rate were increased with the increase of ball clay dosage and initial concentration of Cu(Ⅱ). The pH value had a great impact on the adsorption of ball clay and when the pH value was 6, the adsorption capacity was obtained over 97.93 mg/g. The adsorption of Cu(Ⅱ) on the ball clay followed the Langmiur isotherm model, and the maximum adsorption capacity obtained was 202.383 mg/g. The pseudo-second-order kinetics model was more suitable to describe the adsorption process of Cu(Ⅱ), which indicated that the adsorption rate was controlled by chemisorption. Compared with other pure clay adsorbent materials, the ball clay had a high ability to adsorb copper ions and could be used as a natural mineral adsorbent to treat industrial wastewater containing copper ions.

Key words: ball clay, Cu (Ⅱ), adsorption, isotherm, kinetics

CLC Number: 

  • TU432

Fig.1

Ball clay"

Fig.2

The X-ray diffraction analysis of ball clay"

Table 1

Physical properties of the ball clay"

液限/% 塑限/% 塑性指数 密度/(g·cm-3) 最优含水率/% 最大干密度/(g·cm-3)
40 21 19 2.7 17.7 1.73

Table 2

Batch test scheme for Cu(Ⅱ)"

编号 吸附时间/min 球黏土用量/g 溶液pH值 Cu(Ⅱ)质量浓度/(mg·L-1)
A1 10~150 0.10 6 100
A2 60 0.04~0.50 6 100
A3 60 0.10 2~6 100
A4 60 0.10 6 10~500

Fig.3

Effect of adsorption time on adsorption"

Fig.4

Effect of ball clay dosage on adsorption"

Fig.5

Effect of pH on adsorption"

Fig.6

Effect of initial concentration on adsorption"

Fig.7

Adsorption kinetics model fitting curve of ball clay"

Table 3

Kinetic parameters for Cu(Ⅱ) adsorption on ball clay"

准一阶动力学模型 准二阶动力学模型 颗粒内扩散模型
qe/(mg·g-1) k1/min-1 R2 qe/(mg·g-1) k2/(g·mg-1·min-1) R2 C/(mg·g-1) kw/(mg·min1/2·g-1) R2
97.118 0.323 0.812 98.082 0.021 0.995 93.820 0.371 0.608

Fig.8

Intraparticle diffusion model for the adsorption kinetic data of a Cu(Ⅱ) onto ball clay"

Fig.9

Adsorption isothermal model fitting curve of ball clay"

Table 4

Langmuir, Freundlich and D-R model parameters for Cu(Ⅱ) adsorption on ball clay"

Langmiur等温吸附模型 Freundlich等温吸附模型 D-R等温吸附模型
qm/(mg·g-1) kL/(L·mg-1) RL R2 n kF/(L·mg-1) R2 qm/(mg·g-1) k/(mol2·J-2) E/(KJ·mol-1) R2
202.383 0.007 94 0.024~0.550 0.982 2.210 10.292 0.917 150.677 0.000 564 29.775 0.967

Table 5

Maximum adsorption capacities of ball clay and others adsorbents"

文献 最大吸附量/(mg·g-1) 吸附剂
[25] 30.00 钠基膨润土
[23] 31.80 蒙脱土
[6] 41.67 马来西亚高岭土
[26] 43.85 钙基膨润土
[27] 55.68 伊朗膨润土
[28] 65.00 碱性钙基膨润土
[29] 149.25 膨润土
本研究 202.383 球黏土
1 刘晓慧. 实施土壤保护构建土壤安全[N]. 中国矿业报, 2015-10-29(6).
LIU Xiaohui. Implement soil protection and build soil safety[N]. China Mining News, 2015-10-29(6).
2 CORUH S , GEYIKCI F . Adsorption of copper(Ⅱ) ions on montmorillonite and sepiolite clays: equilibrium and kinetic studies[J]. Desalination and Water Treatment, 2012, 45 (3): 351- 360.
3 刘海龙, 郭存彪, 何璐红, 等. 废水中重金属离子吸附材料的研究进展[J]. 化工技术与开发, 2021, 50 (3): 51- 54.
doi: 10.3969/j.issn.1671-9905.2021.03.013
LIU Hailong , GUO Cunbiao , HE Luhong , et al. Research progress on adsorption materials of heavy metal ions in wastewater[J]. Technology & Development of Chemical Industry, 2021, 50 (3): 51- 54.
doi: 10.3969/j.issn.1671-9905.2021.03.013
4 ANNA B , KLEOPAS M , CONSTANTINE S , et al. Adsorption of Cd(Ⅱ), Cu(Ⅱ), Ni(Ⅱ) and Pb(Ⅱ) onto natural bentonite: study in mono-and multi-metal systems[J]. Environmental Earth Sciences, 2015, 73 (9): 5435- 5444.
doi: 10.1007/s12665-014-3798-0
5 袁建民. 粘土矿物对重金属离子的吸附能力研究[D]. 石家庄: 河北地质大学, 2018.
YUAN Jianmin. Adsorption ability of clay minerals to heavy metal ions[D]. Shijiazhuang: Hebei GEO University, 2018.
6 CHAI J , AU P , MUBARAK N , et al. Adsorption of heavy metal from industrial wastewater onto low-cost Malaysian kaolin clay-based adsorbent[J]. Environmental Science and Pollution Research, 2020, 27 (12): 13949- 13962.
doi: 10.1007/s11356-020-07755-y
7 FUTALAN C , YANG J , PHATAI P , et al. Fixed-bed adsorption of copper from aqueous media using chitosan-coated bentonite, chitosan-coated sand and chitosan-coated kaolinite[J]. Environmental Science and Pollution Research, 2020, 27, 24659- 24670.
doi: 10.1007/s11356-019-06083-0
8 郭瑞峰, 刘长龄. 吉林球黏土大口钦矿区的开发[J]. 非金属矿, 2007, (3): 47- 50.
doi: 10.3969/j.issn.1000-8098.2007.03.017
GUO Ruifeng , LIU Changling . Development of ball clay from Dakouqin Mining District of Jilin Province[J]. Non-Metallic Mines, 2007, (3): 47- 50.
doi: 10.3969/j.issn.1000-8098.2007.03.017
9 刘长龄, 李生才, 刘钦甫. 论我国球粘土[J]. 天津城市建设学院学报, 2003, (4): 256- 260.
doi: 10.3969/j.issn.1006-6853.2003.04.009
LIU Changling , LI Shengcai , LIU Qinfu . On ball clay in China[J]. Journal of Tianjin Institute of Urban Construction, 2003, (4): 256- 260.
doi: 10.3969/j.issn.1006-6853.2003.04.009
10 RAO R , KASHIFUDDIN M . Adsorption studies of Cd(Ⅱ) on ball clay: comparison with other natural clays[J]. Arabian Journal of Chemistry, 2012, 9 (2): 1233- 1421.
11 CHANTAWONG V , HARVEY N , BASHIKIN V . Comparison of heavy metal adsorptions by Thai kaolin and ball clay[J]. Water, Air, and Soil Pollution, 2003, 11 (4): 111- 125.
12 ZAVALA M , SANTANA H , CORDERO B . Removal of Cr(VI) from water by adsorption using low cost clay-perlite-iron membranes[J]. Journal of Water Process Engineering, 2020, 38 (7): 101672- 101682.
13 VIGLASOVA E , DANO M , GALAMBO M , et al. Investigation of Cu(Ⅱ) adsorption on Slovak bentonites and illite/smectite for agricultural applications[J]. Journal of Radioanalytical and Nuclear Chemistry, 2017, 314 (3): 2425- 2435.
doi: 10.1007/s10967-017-5610-6
14 LI Pam , BRUCE R , HOBDAY M . A pseudo first order rate model for the adsorption of an organic adsorbate in aqueous solution[J]. Journal of Chemical Technology and Biotechnology, 1999, 74 (1): 55- 59.
doi: 10.1002/(SICI)1097-4660(199901)74:1<55::AID-JCTB984>3.0.CO;2-D
15 HO Y , MCKAY G . Pseudo-second order model for sorption processes[J]. Process Biochemistry, 1999, 34 (5): 451- 465.
doi: 10.1016/S0032-9592(98)00112-5
16 郝艳玲, 范福海. 坡缕石黏土吸附Cu2+的动力学[J]. 硅酸盐学报, 2010, 38 (11): 2138- 2142.
HAO Yanling , FAN Fuhai . Adsorption kinetic of copper from aqueous on palygorskite clay[J]. Journal of the Chinese Ceramic Society, 2010, 38 (11): 2138- 2142.
17 张宏, 张敬华. 生物吸附的热力学平衡模型和动力学模型综述[J]. 天中学刊, 2009, 24 (5): 19- 22.
doi: 10.3969/j.issn.1006-5261.2009.05.008
ZHANG Hong , ZHANG Jinghua . Review on thermodynamic equilibrium isotherm and kinetic model of biosorption[J]. Journal of Tianzhong, 2009, 24 (5): 19- 22.
doi: 10.3969/j.issn.1006-5261.2009.05.008
18 TUN H , CHEN C . Isosteric heat of adsorption from thermodynamic Langmuir isotherm[J]. Adsorption Journal of the International Adsorption Society, 2021, 27 (6): 979- 989.
doi: 10.1007/s10450-020-00296-3
19 YANG C . Statistical mechanical study on the Freundlich isotherm equation[J]. Journal of Colloid and Interface Science, 1998, 20 (8): 379- 387.
20 HUSTON N , YANG R . Theoretical basis for the Dubinin-Radushkevitch (D-R) adsorption isotherm equation[J]. Adsorption, 1997, 3 (3): 189- 195.
doi: 10.1007/BF01650130
21 敖翔. 颗粒型4A分子筛/凹凸棒土材料的制备及吸附去除水中Cd(Ⅱ)的研究[D]. 武汉: 武汉科技大学, 2017.
AO Xiang. Study on adsorption of aqueous Cd(Ⅱ) by agranular 4A molecular sieve/attapulgite composite[D]. Wuhan: Wuhan University of Science and Technol-ogy, 2017.
22 WU F , TSENG R , JUANG R . Initial behavior of intraparticle diffusion model used in the description of adsorption kinetics[J]. Chemical Engineering Journal, 2009, 15 (3): 1- 8.
23 BHATTACHARYYA K , GUPTA S . Removal of Cu(Ⅱ) by natural and acid-activated clays: an insight of adsorption isotherm, kinetic and thermodynamics[J]. Desalination, 2011, 27 (2): 66- 75.
24 张林林. 黏土矿物对重金属Pb(Ⅱ)吸附特性研究[D]. 大连: 大连理工大学, 2012.
ZHANG Linlin. Adsorption behaviors of heavy mental Pb(Ⅱ) on clay minerals[D]. Dalian: Dalian University of Technology, 2012.
25 AYUSO E , SANCHEZ A . Removal of heavy metals from waste waters by natural and Na-exchanged bentonites[J]. Clays and Clay Minerals, 2003, 51 (5): 475- 480.
doi: 10.1346/CCMN.2003.0510501
26 汤鹏成, 傅开彬, 钟秋红, 等. 广西田东天然钙基膨润土对Cu(Ⅱ)的吸附性能研究[J]. 非金属矿, 2019, 42 (6): 77- 81.
TANG Pengcheng , FU Kaibin , ZHONG Qiuhong , et al. Research on the adsorption properties of Cu(Ⅱ) on natural Ca-Bentonite from Tiandong, Guangxi[J]. Non-Metallic Mines, 2019, 42 (6): 77- 81.
27 SADEGHALVAD B , KHOSRAVI S , AZADMEHR A . Nonlinear isotherm and kinetics of adsorption of copper from aqueous solutions on bentonite[J]. Russian Journal of Physical Chemistry A, 2016, 90 (11): 2285- 2291.
doi: 10.1134/S0036024416110030
28 施华珍, 刘坤, 汤睿, 等. 有机改性磁性碱性钙基膨润土的制备及对Cu(Ⅱ)和Mn(Ⅱ)的吸附[J]. 化工进展, 2018, 37 (11): 4509- 4521.
SHI Huazhen , LIU Kun , TANG Rui , et al. Organically modification of magnetic alkaline Ca-bentonite and its adsorption for Cu(Ⅱ) and Mn(Ⅱ)[J]. Chemical Industry and Engineering Progress, 2018, 37 (11): 4509- 4521.
29 OWOLABI B , UNUABONAH E . Adsorption of Zn2+ and Cu2+ onto sulphate and phosphate-modified bentonite[J]. Applied Clay Science, 2011, 51 (2): 170- 173.
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